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Determining Vinyl Chloride Strength 

Vinyl Chloride, also called Vinyl Chloride Monomer (VCM), is a highly flammable gas that may cause cancer. It reacts with copper, oxidizers, aluminum, peroxides, iron, steel, air, sunlight, or heat unless it is stabilized by inhibitors such as phenol. 

Why sample VCM?

  • To determine potential contamination and concentration. 

What to Look for in the Sample

  • Hydrochloric acid (HCl), caustic trace chemicals, and moisture. 

How to Safely Take VCM Samples

  • Because VCM is highly toxic, it should be sampled in totally enclosed systems, such as a REVO-BOX. 

Vinyl Chloride

1) Description

Name: ..............................................................................................Vinyl chloride

Chemical Formula: ........................................................................C2H3Cl

CAS No: ..........................................................................................75-01-4

Other Names: ...............................................................................Chloroethene, Chloroethylene, Ethylene monochloride, Monochloroethene, Monochloroethylene, VC, VCM, Vinyl chloride monomer (VCM)

Uses: ...............................................................................................Industrial

Physical state: ..............................................................................Colorless gas or liquid (below 7°F)

Color: ..............................................................................................Colorless

Odor: ...............................................................................................Mild, sweet odor

Boiling Point: ................................................................................-13.9°C (7°F)

Freezing Point: ..............................................................................-160°C (-256°F)

Flash Point: ...................................................................................179°C (-110°F)

Upper Explosive Limit: .................................................................33.0%

Lower Explosive Limit: .................................................................3.6%

Vapor pressure: ..............................................................................3 mmHg

2) Hazards

Flammable Gas
H220: Extremely flammable gas
H350: May cause cancer.
 

Reactivity: Copper, oxidizers, aluminum, peroxides, iron, steel [Note: Polymerizes in air, sunlight, or heat unless stabilized by inhibitors such as phenol. Attacks iron & steel in presence of moisture.]

Specific Hazards related to Sampling: As VCM is highly flammable and a carcinogen, it is important that Operators are protected at all times from accidental spills, splashes and fumes. Ideally, sample systems should be enclosed with an adequate venting system to prevent exposure. Alternatively, it can be sampled using an enclosed system such as a container.

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Two icons indicating the potential dangers: one saying "Flammable" and one saying "Health Hazarad"

3) Sampling Facts

a) Why plants need to sample

Plants need to monitor for potential contamination and concentration

b) What are they looking for/measuring in the sample

HCl, caustic, trace chemicals and moisture. Typically, samples are analyzed using gas chromatography.

 

4) Most common Sample Receptacles

As VCM is extremely toxic, it should be sampled in a totally enclosed system.

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